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Analysis of physical properties of gas hydrate-bearing unconsolidated sediment samples from the ultra-deepwater

《能源前沿(英文)》 2022年 第16卷 第3期   页码 509-520 doi: 10.1007/s11708-021-0786-4

摘要: Marine natural gas hydrate has recently attracted global attention as a potential new clean energy source. Laboratory measurements of various physical properties of gas hydrate-bearing marine sediments can provide valuable information for developing efficient and safe extraction technology of natural gas hydrates. This study presents comprehensive measurement results and analysis of drilled hydrate-bearing sediments samples recovered from Qiongdongnan Basin in the South China Sea. The results show that the gas hydrate in the core samples is mainly methane hydrate with a methane content of approximately 95%, and the other components are ethane and carbon dioxide. The saturation of the samples fluctuates from 2%–60%, the porosity is approximately 38%–43%, and the water content is approximately 30%–50%, which indicate that high water saturation means that timely drainage should be paid attention to during hydrate extraction. In addition, the median diameter of the sediment samples is mainly distributed in the range of 15 to 34 μm, and attention should be paid to the prevention and control of sand production in the mining process. Moreover, the thermal conductivity is distributed in the range of 0.75 to 0.96 W/(m∙K) as measured by the flat plate heat source method. The relatively low thermal conductivity of hydrates at this study site indicates that a combined approach is encouraged for natural gas production technologies. It is also found that clay flakes and fine particles are attached to the surface of large particles in large numbers. Such characteristics will lead to insufficient permeability during the production process.

关键词: natural gas hydrates     physical properties analysis     hydrate-bearing sediments    

Progress and prospect of hydrate-based desalination technology

Jibao ZHANG, Shujun CHEN, Ning MAO, Tianbiao HE

《能源前沿(英文)》 2022年 第16卷 第3期   页码 445-459 doi: 10.1007/s11708-021-0740-5

摘要: With the continuous growth of the population and the improvement of production, the shortage of freshwater has plagued many countries. The use of novel technologies such as desalination to produce fresh water on a large scale has become inevitable in the world. Hydrate-based desalination (HBD) technology has drawn an increasing amount of attention due to its mild operation condition and environmental friendliness. In this paper, literature on hydrate-based desalination is comprehensively analyzed and critically evaluated, focuses on experimental progress in different hydrate formers that have an impact on thermodynamics and dynamics in hydrate formation. Besides, various porous media promotion is investigated. Besides, the hydrate formation morphology and hydrate crystal structure with different hydrate formers are analyzed and compared. Moreover, molecular dynamic simulation is discussed to further understand microscopic information of hydrate formation. Furthermore, simulations of the HBD process by considering the energy consumption are also investigated. In conclusion, the hydrated based desalination is a potential technology to get fresh water in a sustainable way.

关键词: gas hydrates     desalination     crystal morphology     molecular dynamic     cold energy    

天然气水合物开采技术研究现状与展望

李清平,周守为,赵佳飞,宋永臣,朱军龙

《中国工程科学》 2022年 第24卷 第3期   页码 214-224 doi: 10.15302/J-SSCAE-2022.03.022

摘要:

天然气水合物是一种世界公认的最具潜力的清洁能源,目前我国对水合物的勘探开采研究正进入关键突破阶段,南海泥质粉砂天然气水合物成藏机理与赋存规律尚不明晰,开采过程水合物分解相变机制与安全、高效技术仍需进一步探明。本文重点介绍了包括降压开采、固态流化开采等在内的天然气水合物开采技术的研究与应用现状,并通过分析天然气水合物开采技术存在的问题给出了相应的发展建议。研究建议,推动天然气水合物、深部油气等多气源立体开采基础研究和重大工程;强化技术融合,推进理论与实践协同并进;推进天然气水合物中试尺度实验和多场耦合的数值模拟大科学平台建设;建立健全天然气水合物的相关标准等措施,以提升我国天然气水合物开采技术的研发水平和技术成熟度,以期早日实现天然气水合物的大规模商业化开发,服务于我国的能源安全战略。

关键词: 天然气水合物;开采技术;降压;固态流化;联合方法    

深海环境中微塑料与甲烷渗漏的相互作用研究 Article

冯景春, 杨志峰, 周文良, 冯星伟, 魏辅文, 李波, 马传鑫, 张偲, 夏琳琳, 蔡宴朋, 王屹

《工程(英文)》 2023年 第29卷 第10期   页码 159-167 doi: 10.1016/j.eng.2022.08.009

摘要:

微塑料(microplastics, MPs)是人类社会的重要产物,对地球碳循环的影响作用日益显著。海面上漂浮的MPs与已进入海洋的MPs估值之间存在着巨大偏差,因此详细研究海洋MPs的沉积特性是必不可少的。冷泉是富含甲烷流体渗漏的典型地质现象,孕育典型的依赖甲烷生存的化能合成生态系统。本研究采集了冷泉沉积物进行实验研究,实验结果表明,在冷泉的沉积物中存在16种小粒径(<100 μm)MPs,且甲烷渗漏区域的表层沉积物的MPs丰度高于非渗漏区域,表明甲烷渗漏活动有利于MPs的富集、破碎、多样性变化和老化等作用。与此同时,粗糙的MPs表面可促进参与甲烷氧化的电子受体如铁元素的富集,而铁氧化物与甲烷的厌氧氧化(AOM)密切相关。AOM效率决定了海底渗出的甲烷(能否进入大气层,对全球甲烷循环产生至关重要的影响。因为甲烷在20年内的温室效应是CO2的83倍,且深海环境富含天然气水合物,是地球上最大的甲烷储存库。

关键词: 微塑料     甲烷厌氧氧化     冷泉     多样性指标     破碎     天然气水合物    

掺梳形减水剂水泥浆体早期水化产物形貌研究

蒋亚清

《中国工程科学》 2011年 第13卷 第9期   页码 69-75

摘要:

为揭示梳形减水剂对水泥早期水化的影响规律,指导工程应用,通过SEM分析,研究了掺用3种典型结构的梳形减水剂的水泥浆体早期水化产物形貌及其电子特征数据。结果表明,梳形减水剂加速了水泥早期水化反应,且丙烯酸类、马来酸类共聚物分别促进了AFt、AFm的形成。因此,梳形减水剂品种对水泥早期水化和混凝土工程性能具有较大影响,应根据使用要求合理选用,必要时与缓凝剂、引气剂或消泡剂复合使用。

关键词: 梳形减水剂     水泥水化     钙矾石     微观形貌    

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

《能源前沿(英文)》 2023年 第17卷 第3期   页码 428-445 doi: 10.1007/s11708-023-0865-9

摘要: In this work, using fractured shale cores, isothermal adsorption experiments and core flooding tests were conducted to investigate the performance of injecting different gases to enhance shale gas recovery and CO2 geological storage efficiency under real reservoir conditions. The adsorption process of shale to different gases was in agreement with the extended-Langmuir model, and the adsorption capacity of CO2 was the largest, followed by CH4, and that of N2 was the smallest of the three pure gases. In addition, when the CO2 concentration in the mixed gas exceeded 50%, the adsorption capacity of the mixed gas was greater than that of CH4, and had a strong competitive adsorption effect. For the core flooding tests, pure gas injection showed that the breakthrough time of CO2 was longer than that of N2, and the CH4 recovery factor at the breakthrough time (RCH4) was also higher than that of N2. The RCH4 of CO2 gas injection was approximately 44.09%, while the RCH4 of N2 was only 31.63%. For CO2/N2 mixed gas injection, with the increase of CO2 concentration, the RCH4 increased, and the RCH4 for mixed gas CO2/N2 = 8:2 was close to that of pure CO2, about 40.24%. Moreover, the breakthrough time of N2 in mixed gas was not much different from that when pure N2 was injected, while the breakthrough time of CO2 was prolonged, which indicated that with the increase of N2 concentration in the mixed gas, the breakthrough time of CO2 could be extended. Furthermore, an abnormal surge of N2 concentration in the produced gas was observed after N2 breakthrough. In regards to CO2 storage efficiency (Sstorage-CO2), as the CO2 concentration increased, Sstorage-CO2 also increased. The Sstorage-CO2 of the pure CO2 gas injection was about 35.96%, while for mixed gas CO2/N2 = 8:2, Sstorage-CO2 was about 32.28%.

关键词: shale gas     gas injection     competitive adsorption     enhanced shale gas recovery     CO2 geological storage    

A novel methodology for forecasting gas supply reliability of natural gas pipeline systems

Feng CHEN, Changchun WU

《能源前沿(英文)》 2020年 第14卷 第2期   页码 213-223 doi: 10.1007/s11708-020-0672-5

摘要: In this paper, a novel systematic and integrated methodology to assess gas supply reliability is proposed based on the Monte Carlo method, statistical analysis, mathematical-probabilistic analysis, and hydraulic simulation. The method proposed has two stages. In the first stage, typical scenarios are determined. In the second stage, hydraulic simulation is conducted to calculate the flow rate in each typical scenario. The result of the gas pipeline system calculated is the average gas supply reliability in each typical scenario. To verify the feasibility, the method proposed is applied for a real natural gas pipelines network system. The comparison of the results calculated and the actual gas supply reliability based on the filed data in the evaluation period suggests the assessment results of the method proposed agree well with the filed data. Besides, the effect of different components on gas supply reliability is investigated, and the most critical component is identified. For example, the 48th unit is the most critical component for the SH terminal station, while the 119th typical scenario results in the most severe consequence which causes the loss of 175.61×10 m gas when the 119th scenario happens. This paper provides a set of scientific and reasonable gas supply reliability indexes which can evaluate the gas supply reliability from two dimensions of quantity and time.

关键词: natural gas pipeline system     gas supply reliability     evaluation index     Monte Carlo method     hydraulic simulation    

Life-cycle analysis of energy use and greenhouse gas emissions of gas-to-liquid fuel pathway from steelmill off-gas in China by the LanzaTech process

Xunmin OU, Xu ZHANG, Qian ZHANG, Xiliang ZHANG

《能源前沿(英文)》 2013年 第7卷 第3期   页码 263-270 doi: 10.1007/s11708-013-0263-9

摘要: The LanzaTech process can convert carbon monoxide-containing gases produced by industries, such as steel manufacturing, into valuable fuel products. The life-cycle analysis (LCA) of energy use and greenhouse gas emissions from the LanzaTech process has been developed for a Chinese setting using the original Tsinghua China Automotive LCA model along with a customized module developed principally for the process. The LCA results demonstrate that LanzaTech gas-to-liquid (GTL) processing in China’s steel manufacturing is favorable in terms of life-cycle fossil energy and can reduce greenhouse gas emissions by approximately 50% compared with the conventional petroleum gasoline. The LanzaTech process, therefore, shows advantages in both energy-savings and a reduction in greenhouse gas emissions when compared with most bio-ethanol production pathways in China.

关键词: life-cycle analysis (LCA)     gas-to-liquid (GTL)     LanzaTech process    

Latest progress in numerical simulations on multiphase flow and thermodynamics in production of natural gasfrom gas hydrate reservoir

Lin ZUO, Lixia SUN, Changfu YOU

《能源前沿(英文)》 2009年 第3卷 第2期   页码 152-159 doi: 10.1007/s11708-009-0017-x

摘要: Natural gas hydrates are promising potential alternative energy resources. Some studies on the multiphase flow and thermodynamics have been conducted to investigate the feasibility of gas production from hydrate dissociation. The methods for natural gas production are analyzed and several models describing the dissociation process are listed and compared. Two prevailing models, one for depressurization and the other for thermal stimulation, are discussed in detail. A comprehensive numerical method considering the multiphase flow and thermodynamics of gas production from various hydrate-bearing reservoirs is required to better understand the dissociation process of natural gas hydrate, which would be of great benefit to its future exploration and exploitation.

关键词: numerical simulation     natural gas hydrate     dissociation     thermodynamics     multiphase flow    

Key issues in development of offshore natural gas hydrate

Shouwei ZHOU, Qingping LI, Xin LV, Qiang FU, Junlong ZHU

《能源前沿(英文)》 2020年 第14卷 第3期   页码 433-442 doi: 10.1007/s11708-020-0684-1

摘要: As a new clean energy resource in the 21st century, natural gas hydrate is considered as one of the most promising strategic resources in the future. This paper, based on the research progress in exploitation of natural gas hydrate (NGH) in China and the world, systematically reviewed and discussed the key issues in development of natural gas hydrate. From an exploitation point of view, it is recommended that the concepts of diagenetic hydrate and non-diagenetic hydrate be introduced. The main factors to be considered are whether diagenesis, stability of rock skeleton structure, particle size and cementation mode, thus NGHs are divided into 6 levels and used unused exploitation methods according to different types. The study of the description and quantitative characterization of abundance in hydrate enrichment zone, and looking for gas hydrate dessert areas with commercial exploitation value should be enhanced. The concept of dynamic permeability and characterization of the permeability of NGH by time-varying equations should be established. The ‘Three-gas co-production’ (natural gas hydrate, shallow gas, and conventional gas) may be an effective way to achieve early commercial exploitation. Although great progress has been made in the exploitation of natural gas hydrate, there still exist enormous challenges in basic theory research, production methods, and equipment and operation modes. Only through hard and persistent exploration and innovation can natural gas hydrate be truly commercially developed on a large scale and contribute to sustainable energy supply.

关键词: natural gas hydrate exploitation offshore     diagenetic and non-diagenetic hydrate     solid-state fluidization method     dessert in enrichment area     three-gas combined production on gas hydrate abundance    

Active-reactive power scheduling of integrated electricity-gas network with multi-microgrids

《能源前沿(英文)》 2023年 第17卷 第2期   页码 251-265 doi: 10.1007/s11708-022-0857-1

摘要: Advances in natural gas-fired technologies have deepened the coupling between electricity and gas networks, promoting the development of the integrated electricity-gas network (IEGN) and strengthening the interaction between the active-reactive power flow in the power distribution network (PDN) and the natural gas flow in the gas distribution network (GDN). This paper proposes a day-ahead active-reactive power scheduling model for the IEGN with multi-microgrids (MMGs) to minimize the total operating cost. Through the tight coupling relationship between the subsystems of the IEGN, the potentialities of the IEGN with MMGs toward multi-energy cooperative interaction is optimized. Important component models are elaborated in the PDN, GDN, and coupled MMGs. Besides, motivated by the non-negligible impact of the reactive power, optimal inverter dispatch (OID) is considered to optimize the active and reactive power capabilities of the inverters of distributed generators. Further, a second-order cone (SOC) relaxation technology is utilized to transform the proposed active-reactive power scheduling model into a convex optimization problem that the commercial solver can directly solve. A test system consisting of an IEEE-33 test system and a 7-node natural gas network is adopted to verify the effectiveness of the proposed scheduling method. The results show that the proposed scheduling method can effectively reduce the power losses of the PDN in the IEGN by 9.86%, increase the flexibility of the joint operation of the subsystems of the IEGN, reduce the total operation costs by $32.20, and effectively enhance the operation economy of the IEGN.

关键词: combined cooling     heating     and power (CCHP)     integrated energy systems (IES)     natural gas     power distribution system     gas distribution system    

Bioenergy recovery from landfill gas: A case study in China

Wei WANG, Yuxiang LUO, Zhou DENG

《环境科学与工程前沿(英文)》 2009年 第3卷 第1期   页码 20-31 doi: 10.1007/s11783-009-0012-9

摘要: Landfill gas (LFG) utilization which means a synergy between environmental protection and bioenergy recovery was investigated in this study. Pressure swing adsorption technology was used in LFG purification, and laboratory experiment, pilot-scale test, and on-site demonstration were carried out in Shenzhen, China. In the laboratory experiment, A-type carbon molecular sieve was selected as the adsorbent by comparison of several other adsorbents. The optimal adsorption pressure and adsorption time were 0.25 MPa and 2 min, respectively, under which the product generation rate was 4.5 m /h and the methane concentration was above 90%. The process and optimization of the pilot-scale test were also reported in the paper. The product gas was of high quality compared with the National Standard of Compressed Natural Gas as Vehicle Fuel (GB18047-2000), when the air concentration in feed gas was under 10.96%. The demonstration project was composed of a collection system, production system, and utilization system. The drive performance, environmental protection performance, and economic feasibility of the product gas – as alternative fuel in passenger car, truck, and bulldozer – were tested, showing the feasibility technology for LFG utilization.

关键词: landfill gas (LFG)     compressed purified landfill gas (CPLG)     pressure swing adsorption (PSA)     alternative vehicle fuel     demonstration project    

The Fast Road of Shale Gas Development in China —Reflections on Building a Special Test Areas for NationalShale Gas Development

Da-wei Zhang

《工程管理前沿(英文)》 2015年 第2卷 第4期   页码 364-372 doi: 10.15302/J-FEM-2015062

摘要: China’s shale gas development has had a good start. It is necessary that the developers take advantage of the opportunity to make further efforts to promote shale gas development in China, in particular by rolling out a comprehensive plan on a national level. The author makes a proposal to establish a special shale gas test area in and adjacent to the Sichuan Basin as the most important way to promote the rapid development of shale gas in China. For this purpose, the author analyzes the current situation and problems of shale gas development in China, addresses the necessity and feasibility of establishing a special test area for shale gas development, and draws up the scope of this shale gas special test area of about 450 thousand square kilometers, covering Sichuan, Chongqing, Guizhou, and part of Yunnan, Hunan, Hubei provinces, and proposes the establishment of a shale gas test area in China. This consists of an overall plan, targets, and contents in 10 aspects, along with organization and implementation modes. The shale gas exploration and development in the shale gas zones is promoted vigorously by introducing special policies and innovating exploration, development and utilization model. While at the same time, the shale gas zones of continental facies in the Ordos Basin and marine-terrigenous facies in South Hubei Basin will be established. The experiences of the reform in the shale gas zones will be the good practice for the reform of petroleum organization system.

关键词: China     shale gas     exploration and development     reform     special shale gas test area (shale gas zone)    

Technology Innovation and Practice of Green Exploitation Projects of Oil and Gas in the Western SichuanGas Field

Hong-yong Liu,Yi-qi Chen,Yi Yang

《工程管理前沿(英文)》 2015年 第2卷 第1期   页码 71-75 doi: 10.15302/J-FEM-2015010

摘要: The green (environmentally friendly) project of mining oil and gas in the Western Sichuan area is based on the green low-carbon development strategy of the China Petrochemical Corporation, and it commits to form a complete set of technological developments in oil and gas extraction processes. The project focuses on technology innovation in three aspects: reuse of fracturing flow back fluid, reuse of drilling fluid, and configuration of fracturing fluid and drilling fluid by formation water. A series of technology innovations not only realize the green low-carbon strategy of the enterprise, but also play an important role in lowering cost and improving efficiency. In addition, the technology achieves remarkable social and economic benefits and inspires the ideas for industry technology innovation.

关键词: oil and gas exploitation     green low-carbon     technology innovation     strategic thinking    

GREENHOUSE GAS AND AMMONIA EMISSION MITIGATION PRIORITIES FOR UK POLICY TARGETS

《农业科学与工程前沿(英文)》 2023年 第10卷 第2期   页码 268-280 doi: 10.15302/J-FASE-2023495

摘要:

● An expert survey highlighted the most effective strategies for GHG and ammonia mitigation.

关键词: agriculture     ammonia     greenhouse gas     mitigation     net zero    

标题 作者 时间 类型 操作

Analysis of physical properties of gas hydrate-bearing unconsolidated sediment samples from the ultra-deepwater

期刊论文

Progress and prospect of hydrate-based desalination technology

Jibao ZHANG, Shujun CHEN, Ning MAO, Tianbiao HE

期刊论文

天然气水合物开采技术研究现状与展望

李清平,周守为,赵佳飞,宋永臣,朱军龙

期刊论文

深海环境中微塑料与甲烷渗漏的相互作用研究

冯景春, 杨志峰, 周文良, 冯星伟, 魏辅文, 李波, 马传鑫, 张偲, 夏琳琳, 蔡宴朋, 王屹

期刊论文

掺梳形减水剂水泥浆体早期水化产物形貌研究

蒋亚清

期刊论文

CO, N, and CO/N mixed gas injection for enhanced shale gas recovery and CO geological storage

期刊论文

A novel methodology for forecasting gas supply reliability of natural gas pipeline systems

Feng CHEN, Changchun WU

期刊论文

Life-cycle analysis of energy use and greenhouse gas emissions of gas-to-liquid fuel pathway from steelmill off-gas in China by the LanzaTech process

Xunmin OU, Xu ZHANG, Qian ZHANG, Xiliang ZHANG

期刊论文

Latest progress in numerical simulations on multiphase flow and thermodynamics in production of natural gasfrom gas hydrate reservoir

Lin ZUO, Lixia SUN, Changfu YOU

期刊论文

Key issues in development of offshore natural gas hydrate

Shouwei ZHOU, Qingping LI, Xin LV, Qiang FU, Junlong ZHU

期刊论文

Active-reactive power scheduling of integrated electricity-gas network with multi-microgrids

期刊论文

Bioenergy recovery from landfill gas: A case study in China

Wei WANG, Yuxiang LUO, Zhou DENG

期刊论文

The Fast Road of Shale Gas Development in China —Reflections on Building a Special Test Areas for NationalShale Gas Development

Da-wei Zhang

期刊论文

Technology Innovation and Practice of Green Exploitation Projects of Oil and Gas in the Western SichuanGas Field

Hong-yong Liu,Yi-qi Chen,Yi Yang

期刊论文

GREENHOUSE GAS AND AMMONIA EMISSION MITIGATION PRIORITIES FOR UK POLICY TARGETS

期刊论文